Abstract:An approach remote control arsenic fluoride ion automatic detection system based on Labview was described, the article mainly introduce the overall technical route, liquid instrument automatic sampling, sampling circuit, control software and signal processing. When the measured arsenic, fluoride content in water environment changes, the three electrode method to detect the automatic current changes, and then through the noise analysis method and the peak signal based on wavelet analysis area calculation method to calculate the ion concentration of the corresponding. The experimental results indicate the index of fluorine content minimum resolution is 0.2ppm, the detection range is 0.2~50ppm; detection index for arsenic minimum resolution is 0.1ppb, the detection range is 1~500ppb. The instrument is possible for detecting harmful ions in drinking water on-site monitoring of real-time.